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Definition of bond-dissociation energy, D (SI unit: kJ mol-1, or J (per molecule))

  1. The enthalpy (per mole) required to break a given bond of some specific molecular entity by homolysis, e.g. forCH4 [arrow] H3C. + H.symbolized as D(CH3-H) (cf. heterolytic bond-dissociation energy). See also bond energy.