Definition of spectator mechanism

1. A pre-association mechanism in which one of the molecular entities, C, is already present in an encounter pair with A during formation of B from A, but does not assist the formation of B, e.g.

   

   The formation of B from A may itself be a bimolecular reaction with some other reagent. Since C does not assist the formation of A, it is described as being present as a spectator, and hence such a mechanism is sometimes referred to as a spectator mechanism. See also microscopic diffusion control .