21
Sc
44.9559
Scandium
General | States | Energies
Oxidation & Electrons | Appearance & Characteristics
Reactions | Compounds | Radius | Conductivity
Abundance & Isotopes

Scandium
Scandium
(Photo: Gibe, GNU Free Documentation License).




General:

Name: Scandium Symbol: Sc
Type: Transition Metal Atomic weight: 44.9559
Density @ 293 K: 3.0 g/cm3 Atomic volume: 15.0 cm3/mol
Discovered: Scandium was discovered by Lars F. Nilson in 1879 using spectral analysis of the minerals euxenite and gadolinite. The element is named after the Latin word 'Scanda', meaning Scandinavia because the element occurs in rare minerals found there.

States

State (s, l, g): solid
Melting point: 1813.2 K   (1540 oC) Boiling point: 3103 K   (2830 oC)

Energies

Specific heat capacity: 0.6 J g-1 K-1 Heat of atomization: 378 kJ mol-1
Heat of fusion: 14.10 kJ mol-1 Heat of vaporization : 314.20 kJ mol-1
1st ionization energy: 631 kJ mol-1 2nd ionization energy: 1235 kJ mol-1
3rd ionization energy: 2389 kJ mol-1 Electron affinity: 18.1 kJ mol-1

Oxidation & Electrons

Shells: 2,8,9,2 Electron configuration: [Ar] 3d1 4s2
Minimum oxidation number: 0 Maximum oxidation number: 3
Min. common oxidation no.: 0 Max. common oxidation no.: 3
Electronegativity (Pauling Scale): 1.36 Polarizability volume: 17.8 Å3

Appearance & Characteristics

Structure: hcp: hexagonal close pkd Color: silvery-white
Harmful effects: Scandium is a suspected carcinogen. Hardness: mohs

Scandium is an element which chemists usually ignore!

Characteristics:
Scandium is a soft, light, silvery-white metal, which becomes slightly tinged with yellow or pink when exposured to air. Scandium is almost as light (low density) as aluminum but it has a much higher melting point. It is therefore of potential specialty use in aircraft - scandium will not be used generally because it is much more expensive than aluminum. Scandium reacts with many acids.

Uses:
Scandium is used in aluminum-scandium alloys for aerospace industry components and for sports equipment. It is used to make high intensity lights and light bulbs. The radioactive isotope 45Sc is used in oil refineries as a tracing agent.

Reactions

Reaction with air: vigorous, ⇒ Sc2O3 Reaction with 6 M HCl: mild, ⇒ H2, ScCl3
Reaction with 15 M HNO3: mild , ⇒ Sc(NO3)3 Reaction with 6 M NaOH: none

Compounds

Oxide(s): Sc2O3 Chloride(s): ScCl3
Hydride(s): ScHsub2, ScH3

Radius

Atomic radius: 162pm Ionic radius (1+ ion): pm
Ionic radius (2+ ion): pm Ionic radius (3+ ion): 88.5 pm
Ionic radius (2- ion): pm Ionic radius (1- ion): pm

Conductivity

Thermal conductivity: 15.8 W m-1 K-1 Electrical conductivity: 1.5 x 10-6 S m-1

Abundance & Isotopes

Abundance earth's crust: 22 parts per million by weight, 10 parts per million by moles
Abundance solar system: 40 parts per billion by weight, 1 part per billion by moles
Cost, pure: $1400 per 100g
Cost, bulk: $ per 100g
Source: Scandium is not found free in nature but is found combined in minute anmounts in over 800 minerals. Rare minerals from Scandinavia and Madagascar (thortveitite, euxenite, and gadolinite) are the only known concentrated sources of the element. Commercially, scandium is obtained as a by-product of uranium refining.
Isotopes: Scandium has 13 isotopes whose half-lives are known, with mass numbers 40 to 52. Of these, one is stable: 45Sc.