Definition of Molecularity

What is Molecularity?

The number of reactant molecular entities that are involved in the "microscopic chemical event" constituting an elementary reaction.

(For reactions in solution this number is always taken to exclude molecular entities that form part of the medium and which are involved solely by virtue of their solvation of solutes.)

A reaction with a molecularity of one is called "unimolecular", one with a molecularity of two "bimolecular" and of three "termolecular".

See also chemical reaction, order of reaction.


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