38
Sr
87.62
Strontium
General | States | Energies
Oxidation & Electrons | Appearance & Characteristics
Reactions | Compounds | Radius | Conductivity
Abundance & Isotopes

Strontium
Strontium
(Photo: Matthias Zepper)




General:

Name: Strontium Symbol: Sr
Type: Alkali Earth Metal Atomic weight: 87.62
Density @ 293 K: 2.6 g/cm3 Atomic volume: 33.7 cm3/mol
Discovered: Strontium was recognized as distinct from barium in 1790 by Adair Crawford in a mineral sample from a mine near Strontian, Scotland. The element took its name from the Scottish town. The metal was first isolated by Sir Humphry Davy in 1808, by electrolysis.

States

State (s, l, g): solid
Melting point: 1050 K   (777 oC) Boiling point: 1653 K   (1380 oC)

Energies

Specific heat capacity: 0.30 J g-1 K-1 Heat of atomization: 164 kJ mol-1
Heat of fusion: 8.30 kJ mol-1 Heat of vaporization : 144.0 kJ mol-1
1st ionization energy: 549.5 kJ mol-1 2nd ionization energy: 1064.2 kJ mol-1
3rd ionization energy: 4138 kJ mol-1 Electron affinity: 5 kJ mol-1

Oxidation & Electrons

Shells: 2,8,18,8,2 Electron configuration: [Kr] 5s2
Minimum oxidation number: 0 Maximum oxidation number: 2
Min. common oxidation no.: 0 Max. common oxidation no.: 2
Electronegativity (Pauling Scale): 0.95 Polarizability volume: 27.6 Å3

Appearance & Characteristics

Structure: ccp: cubic close-packed Color: silvery
Hardness: 1.5 mohs

Strontium metal burns in air with a distinctive red flame, forming a mixture of strontium oxide and nitride.

The world's most accurate atomic clock, based on strontium atoms, would neither gain nor lose a second in more than 200 million years.

Harmful effects:
Strontium's non-radioactive isotopes are considered non-toxic.

As a result of its chemical similarity to its fellow Group 2 element, calcium, strontium replaces and mimics calcium in the human body. Absorption of the radioactive isotope 90Sr, distributed due to fallout from nuclear tests, can lead to various bone disorders and diseases.

Characteristics:
Strontium is a soft, silvery metal. When cut it quickly turns a yellowish color due to the formation of strontium oxide (strontia, SrO) . Finely powdered strontium metal is sufficiently reactive to ignite spontaneously in air.

It reacts with water quickly (but not violently like the Group 1 metals) to produce strontium hydroxide and hydrogen gas.

Strontium and its compounds burn with a crimson flame and are used in fireworks.

Uses:
Strontium is used for producing glass (cathode ray tubes) for color televisions. It is also used in producing ferrite ceramic magnets and in refining zinc.

The world's most accurate atomic clock, accurate to one second in 200 million years, has been developed using strontium atoms.

Strontium salts are used in flares and fireworks for a crimson color.

Strontium chloride is used in toothpaste for sensitive teeth.

Strontium oxide is used to improve the quality of pottery glazes.

The isotope 90Sr is one of the best long-lived, high-energy beta emitters known. It is used in cancer therapy.

Reactions

Reaction with air: vigorous, ⇒ SrO, Sr2N3 Reaction with 6 M HCl: vigorous, ⇒ H2, SrCl2
Reaction with 15 M HNO3: vigorous, ⇒ H2, Sr(NO3)2 Reaction with 6 M NaOH: vigorous, ⇒ none

Compounds

Oxide(s): SrO, SrO2 (strontium peroxide) Chloride(s): SrCl2
Hydride(s): SrH2

Radius

Atomic radius: 215 pm Ionic radius (1+ ion): pm
Ionic radius (2+ ion): 132 pm Ionic radius (3+ ion): pm
Ionic radius (2- ion): pm Ionic radius (1- ion): pm

Conductivity

Thermal conductivity: 35.4 W m-1 K-1 Electrical conductivity: 5 x 10-6 S m-1

Abundance & Isotopes

Abundance earth's crust: 370 parts per million by weight, 87 parts per million by moles
Abundance solar system: 50 parts per billion by weight, 0.7 parts per billion by moles
Cost, pure: $100 per 100g
Cost, bulk: $ per 100g
Source: Strontium is never found free in nature. The principal strontium ores are celestine (strontium sulfate, SrSO4) and strontianite (strontium carbonate, SrCO3). The main commercial process for strontium metal production is reduction of strontium oxide with aluminum.
Isotopes: Strontium has 28 isotopes whose half-lives are known, with mass numbers 75 to 102. Of these, four are stable: 84Sr, 86Sr, 87Sr and 88Sr. 88Sr is the most abundant in nature at 82.6%.